Effect of feedstock solvent on the stability of Cu/SiO2 catalyst for vapor-phase hydrogenation of dimethyl oxalate to ethylene glycol.
نویسندگان
چکیده
The lifetime (200 h) of a Cu/SiO(2) catalyst under DMO-ethanol feedstock is 20 times longer than that (10 h) of the catalyst under DMO-methanol feedstock without any modification of the catalyst. The stabilization effect of ethanol on the active centers can effectively slow down the agglomeration of copper particles during the hydrogenation process.
منابع مشابه
Solvent feedstock effect: the insights into the deactivation mechanism of Cu/SiO2 catalysts for hydrogenation of dimethyl oxalate to ethylene glycol.
The variation of the supports on the Cu/SiO2 catalyst plays an important role in the catalytic performance for hydrogenation of dimethyl oxalate. The loss of silica in the form of tetramethoxysilane from the support under the reaction conditions is responsible for the deactivation of the Cu/SiO2 catalyst.
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 8 شماره
صفحات -
تاریخ انتشار 2012